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PVC (polyvinyl chloride) foils with a PVDC (polyvinylidene chloride) coating are often used for high performance packaging films like pharmaceutical blister packs or in food packaging. In multi-layer blister films, the PVC serves as the thermoformable backbone structure, whereas the PVDC coating acts as a barrier against moisture and oxygen. The Water Vapor Transmission Rate (WVTR) and Oxygen Transmission Rate (OTR) are influenced by the composition and the thickness of the coating.

A fast way to monitor PVDC coating thickness is with near-infrared spectroscopy. Results are provided in a few seconds, indicating when adjustments in the polymer production process are necessary.

DS2500 Solid Analyzer
Figure 1. DS2500 Solid Analyzer

Several 250 μm PVC foils coated with a PVDC layer of varying thickness (40 g/m2 , 60 g/m2 , 90 g/m2) were measured on the DS2500 Solid Analyzer. The measurements were carried out in transflection mode using the NIRS gold diffuse reflector with 1 mm pathlength. This ensures that the spectral pathlength is constant while enhancing the spectral signal. The Metrohm software package Vision Air Complete was used for all data acquisition and prediction model development. 

Table 1. Hardware and software equipment overview
Equipment Metrohm number
NIRS DS2500 Solid Analyzer 2.922.0010
Vision Air 2.0 Complete 6.6072.208 
NIRS gold diffuse reflector, 1 mm 6.7420.000 
NIRS mini sample cup 6.7402.030 

All 68 measured Vis-NIR spectra (Figure 2) were used to create a prediction model for quantification of PVDC layer thickness. The quality of the prediction model was evaluated using correlation diagrams, which display a very high correlation between Vis-NIR prediction and the reference values. The respective figures of merit (FOM) display the expected precision of a prediction during routine analysis.

Figure 2. Vis-NIR spectra of PVC foils with different PVDC layer thicknesses measured on a DS2500 Solid Analyzer.
Figure 3. Correlation diagram for the prediction of PVDC layer thickness using a DS2500 Solid Analyzer.
Table 2. Figures of merit for the prediction of PVDC layer thickness using a DS2500 Solid Analyzer.
Figures of merit Value
R2 0.992
Standard error of calibration 1.7 g/m2
Standard error of cross-validation 1.9 g/m2

This application note demonstrates the feasibility of differentiating PVC foils coated with different PVDC layer thickness (40, 60, 90 g/m2 PVDC on 250 μm PVC foils). The thickness of the PVDC layer could be successfully determined with NIR spectroscopy with an average difference with respect to the reference data of 2%. Vis-NIR spectroscopy enables a fast determination without any sample preparation, and therefore represents a suitable method to measure PVDC layer thickness.

Author

Metrohm Slovensko, s.r.o.

Galvaniho 12
82104 Bratislava

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