环氧丙烷 (PO) 是一种从原油中提取的无色但极易燃的液体。环氧丙烷有多种工业用途，但大部分用于生产多元醇，而多元醇是聚醚多元醇（如泡沫、涂料、粘合剂）和丙二醇（如 PET 瓶、纤维、家具）的基本成分。

目前有多种生产工艺可用于制造 PO。其中一些工艺会产生副产品（如氯海德林 “CH-PO”、苯乙烯 “SM-PO ”和甲基叔丁基醚 “MTBE-PO”），而另一些工艺则不产生衍生物（如过氧化氢 “HP-PO ”和积炭 “CU-PO”）。在这些工艺中，HP-PO 被认为对环境的影响非常小。

由于生产环境的危险性，本工艺应用说明重点介绍使用防爆工艺分析仪在线监测过氧化氢 (_H2O2) 的 HP-PO 工艺。在线分析有助于提高环氧丙烷的产量，同时以较低的原料消耗降低成本，并确保在这一高度危险工艺中工作的操作人员有一个安全的工作环境。

Propylene oxide (PO) is an important intermediate product for several markets because of its wide range of applications that are predominantly used in the polyurethane and solvent industries.

The global production of PO is more than 10 million tons per year [1]. This market is still growing and with it the need for a more cost efficient and environmentally friendly production process. PO production methods are available both with and without byproduct materials (Table 1). Depending on the market for these byproducts, one or more of these processes may be in major use globally at any time.

H₂O₂ present in a methanol solvent is used as the sole oxidizing agent and is the critical feedstock and key parameter to measure the complete conversion rate to PO. Thus, there is a high demand for accurate and robust online process monitoring throughout the whole HP-PO reaction process.

Considering the dangerous nature of this process, online measurement techniques are key for safety reasons. H₂O₂ can be accurately monitored in the effluent of the primary reactor using an online analysis solution designed for extremely hazardous areas (Figure 1). 

Additionally, analyzing the residual H₂O₂ concentrations in finishing reactor overheads upstream of the propene recovery section ensures that unreacted hydrogen peroxide is closely monitored for control measures after the epoxidation reactor (Figure 1).

Due to the hazardous environment at these production plants, strict safety precautions have to be implemented with all production and process equipment. The ADI 2045TI Ex proof (ATEX) Process Analyzer from Metrohm Process Analytics (Figure 2) complies to all electrical safety requirements and is specifically designed for high throughput processing in hazardous locations.

1.  Kawabata, T.; Yamamoto, J.; Koike, H.; Yoshida, S. Trends and Views in the Development of Technologies for Propylene Oxide Production; Sumitomo Kagaku, 2019; pp 4–11.